Ligand-induced substrate steering and reshaping of [Ag(2)(H)](+) scaffold for selective CO(2) extrusion from formic acid

Metalloenzymes preorganize the reaction environment to steer substrate(s) along the required reaction coordinate. Here, we show that phosphine ligands selectively facilitate protonation of binuclear silver hydride cations, [LAg(2)(H)](+) by optimizing the geometry of the active site. This is a key s...

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Detalles Bibliográficos
Autores principales: Zavras, Athanasios, Khairallah, George N., Krstić, Marjan, Girod, Marion, Daly, Steven, Antoine, Rodolphe, Maitre, Philippe, Mulder, Roger J., Alexander, Stefanie-Ann, Bonačić-Koutecký, Vlasta, Dugourd, Philippe, O'Hair, Richard A. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4897753/
https://www.ncbi.nlm.nih.gov/pubmed/27265868
http://dx.doi.org/10.1038/ncomms11746

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4897753/
https://www.ncbi.nlm.nih.gov/pubmed/27265868
http://dx.doi.org/10.1038/ncomms11746

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