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Entropy and Fragility in Supercooling Liquids
We review the Kauzmann paradox and what it implies about the configuration space energy hypersurface for “structural glassformers.” With this background, we then show how the relaxation expression of Adam and Gibbs qualitatively accounts for most of the phenomenology of liquid and polymeric glassfor...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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[Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology
1997
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4900877/ https://www.ncbi.nlm.nih.gov/pubmed/27805135 http://dx.doi.org/10.6028/jres.102.013 |