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Selective, Tunable O(2) Binding in Cobalt(II)–Triazolate/Pyrazolate Metal–Organic Frameworks

[Image: see text] The air-free reaction of CoCl(2) with 1,3,5-tri(1H-1,2,3-triazol-5-yl)benzene (H(3)BTTri) in N,N-dimethylformamide (DMF) and methanol leads to the formation of Co-BTTri (Co(3)[(Co(4)Cl)(3)(BTTri)(8)](2)·DMF), a sodalite-type metal–organic framework. Desolvation of this material gen...

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Detalles Bibliográficos
Autores principales: Xiao, Dianne J., Gonzalez, Miguel I., Darago, Lucy E., Vogiatzis, Konstantinos D., Haldoupis, Emmanuel, Gagliardi, Laura, Long, Jeffrey R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4901364/
https://www.ncbi.nlm.nih.gov/pubmed/27180991
http://dx.doi.org/10.1021/jacs.6b03680