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Dynamic behavior of rearranging carbocations – implications for terpene biosynthesis

This review describes unexpected dynamical behaviors of rearranging carbocations and the modern computational methods used to elucidate these aspects of reaction mechanisms. Unique potential energy surface topologies associated with these rearrangements have been discovered in recent years that are...

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Detalles Bibliográficos
Autores principales: Hare, Stephanie R, Tantillo, Dean J
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4902080/
https://www.ncbi.nlm.nih.gov/pubmed/27340434
http://dx.doi.org/10.3762/bjoc.12.41