Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism

The palladium-catalysed allylic substitution reaction is one of the most important reactions in transition-metal catalysis and has been well-studied in the past decades. Most of the reactions proceed through an outer-sphere mechanism, affording linear products when monosubstituted allyl reagents are...

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Detalles Bibliográficos
Autores principales: Bai, Da-Chang, Yu, Fei-Le, Wang, Wan-Ying, Chen, Di, Li, Hao, Liu, Qing-Rong, Ding, Chang-Hua, Chen, Bo, Hou, Xue-Long
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4906412/
https://www.ncbi.nlm.nih.gov/pubmed/27283477
http://dx.doi.org/10.1038/ncomms11806

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4906412/
https://www.ncbi.nlm.nih.gov/pubmed/27283477
http://dx.doi.org/10.1038/ncomms11806

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