Mechanism of the Transmetalation of Organosilanes to Gold

Density functional theory (DFT) calculations were carried out to study the reaction mechanism of the first transmetalation of organosilanes to gold as a cheap fluoride‐free process. The versatile gold(I) complex [Au(OH)(IPr)] permits very straightforward access to a series of aryl‐, vinyl‐, and alky...

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Detalles Bibliográficos
Autores principales: Falivene, Laura, Nelson, David J., Dupuy, Stéphanie, Nolan, Steven P., Poater, Albert, Cavallo, Luigi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2015
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4906480/
https://www.ncbi.nlm.nih.gov/pubmed/27308213
http://dx.doi.org/10.1002/open.201500172

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4906480/
https://www.ncbi.nlm.nih.gov/pubmed/27308213
http://dx.doi.org/10.1002/open.201500172

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