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On the Reaction Mechanism of the Rhodium‐Catalyzed Arylation of Fullerene (C(60)) with Organoboron Compounds in the Presence of Water

Density functional theory (DFT) calculations were carried out to study the reaction mechanism of the Suzuki–Miyaura rhodium‐catalyzed hydroarylation of fullerene (C(60)) by phenylboronic acid in the presence of water. As found experimentally, our results confirm that addition of the phenyl group and...

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Detalles Bibliográficos
Autores principales: Martínez, Juan Pablo, Solà, Miquel, Poater, Albert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4906499/
https://www.ncbi.nlm.nih.gov/pubmed/27308203
http://dx.doi.org/10.1002/open.201500093