Crystal structure of the inverse crown ether tetra­kis­[μ(2)-bis­(tri­methyl­sil­yl)amido]-μ(4)-oxido-dicobalt(II)disodium, [Co(2)Na(2){μ(2)-N(SiMe(3))(2)}(4)](μ(4)-O)

The title compound, [Co(2)Na(2){μ(2)-N(SiMe(3))(2)}(4)](μ(4)-O), (I), represents a new entry in the class of inverse crown ethers. In the mol­ecule, each Co atom is formally in the oxidation state +II. The structure contains one half of a unique mol­ecule per asymmetric unit with the central μ(4)-ox...

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Detalles Bibliográficos
Autores principales: Hansen, Christopher B., Filatov, Alexander S., Hillhouse, Gregory L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908559/
https://www.ncbi.nlm.nih.gov/pubmed/27308041
http://dx.doi.org/10.1107/S2056989016006861

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908559/
https://www.ncbi.nlm.nih.gov/pubmed/27308041
http://dx.doi.org/10.1107/S2056989016006861

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