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Crystal structure of bis­[μ-2-(diiso­propyl­phosphor­yl)propan-2-olato-κ(3) O (1),O (2):O (1)]bis­[chlorido­oxidovanadium(IV)]

The dinuclear mol­ecule of the title complex, [VOCl{μ-OC(Me)(2)P(iPr)(2)-κ(2) O}](2) or [V(2)(C(9)H(20)O(2)P)(2)Cl(2)O(2)], which was obtained due to an unexpected oxidation reaction, is centrosymmetric, with the inversion centre located in the middle of the central V(2)O(2) core. These core O atoms...

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Detalles Bibliográficos
Autores principales: Glatz, Mathias, Stöger, Berthold, Weil, Matthias, Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908574/
https://www.ncbi.nlm.nih.gov/pubmed/27308042
http://dx.doi.org/10.1107/S2056989016007362