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Crystal structure of tetrakis[μ(2)-2-(dimethylamino)ethanolato-κ(3) N,O:O]di-μ(3)-hydroxido-dithiocyanato-κ(2) N-dichromium(III)dilead(II) dithiocyanate acetonitrile monosolvate
The tetranuclear complex cation of the title compound, [Cr(2)Pb(2)(NCS)(2)(OH)(2)(C(4)H(10)NO)(4)](SCN)(2)·CH(3)CN, lies on an inversion centre. The main structural feature of the cation is a distorted seco-norcubane Pb(2)Cr(2)O(6) cage with a central four-membered Cr(2)O(2) ring. The Cr(III) ion i...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910341/ https://www.ncbi.nlm.nih.gov/pubmed/27375871 http://dx.doi.org/10.1107/S2056989016003996 |