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Highly Unsaturated Platinum and Palladium Carbenes PtC(3) and PdC(3) Isolated and Characterized in the Gas Phase
Carbenes of platinum and palladium, PtC(3) and PdC(3), were generated in the gas phase through laser vaporization of a metal target in the presence of a low concentration of a hydrocarbon precursor undergoing supersonic expansion. Rotational spectroscopy and ab initio calculations confirm that both...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4950143/ https://www.ncbi.nlm.nih.gov/pubmed/27478275 http://dx.doi.org/10.1002/ange.201511646 |