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Highly Unsaturated Platinum and Palladium Carbenes PtC(3) and PdC(3) Isolated and Characterized in the Gas Phase

Carbenes of platinum and palladium, PtC(3) and PdC(3), were generated in the gas phase through laser vaporization of a metal target in the presence of a low concentration of a hydrocarbon precursor undergoing supersonic expansion. Rotational spectroscopy and ab initio calculations confirm that both...

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Detalles Bibliográficos
Autores principales: Bittner, Dror M., Zaleski, Daniel P., Tew, David P., Walker, Nicholas R., Legon, Anthony C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4950143/
https://www.ncbi.nlm.nih.gov/pubmed/27478275
http://dx.doi.org/10.1002/ange.201511646