Highly Unsaturated Platinum and Palladium Carbenes PtC(3) and PdC(3) Isolated and Characterized in the Gas Phase

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Carbenes of platinum and palladium, PtC(3) and PdC(3), were generated in the gas phase through laser vaporization of a metal target in the presence of a low concentration of a hydrocarbon precursor undergoing supersonic expansion. Rotational spectroscopy and ab initio calculations confirm that both...

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Autores principales: Bittner, Dror M., Zaleski, Daniel P., Tew, David P., Walker, Nicholas R., Legon, Anthony C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Zuschriften
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4950143/
https://www.ncbi.nlm.nih.gov/pubmed/27478275
http://dx.doi.org/10.1002/ange.201511646
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author Bittner, Dror M.
Zaleski, Daniel P.
Tew, David P.
Walker, Nicholas R.
Legon, Anthony C.
author_facet Bittner, Dror M.
Zaleski, Daniel P.
Tew, David P.
Walker, Nicholas R.
Legon, Anthony C.
author_sort Bittner, Dror M.
collection PubMed
description Carbenes of platinum and palladium, PtC(3) and PdC(3), were generated in the gas phase through laser vaporization of a metal target in the presence of a low concentration of a hydrocarbon precursor undergoing supersonic expansion. Rotational spectroscopy and ab initio calculations confirm that both molecules are linear. The geometry of PtC(3) was accurately determined by fitting to the experimental moments of inertia of twenty‐six isotopologues. The results are consistent with the proposal of an autogenic isolobal relationship between O, Au(+), and Pt atoms.
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spelling pubmed-49501432016-07-28 Highly Unsaturated Platinum and Palladium Carbenes PtC(3) and PdC(3) Isolated and Characterized in the Gas Phase Bittner, Dror M. Zaleski, Daniel P. Tew, David P. Walker, Nicholas R. Legon, Anthony C. Angew Chem Weinheim Bergstr Ger Zuschriften Carbenes of platinum and palladium, PtC(3) and PdC(3), were generated in the gas phase through laser vaporization of a metal target in the presence of a low concentration of a hydrocarbon precursor undergoing supersonic expansion. Rotational spectroscopy and ab initio calculations confirm that both molecules are linear. The geometry of PtC(3) was accurately determined by fitting to the experimental moments of inertia of twenty‐six isotopologues. The results are consistent with the proposal of an autogenic isolobal relationship between O, Au(+), and Pt atoms. John Wiley and Sons Inc. 2016-02-15 2016-03-07 /pmc/articles/PMC4950143/ /pubmed/27478275 http://dx.doi.org/10.1002/ange.201511646 Text en © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution (http://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Zuschriften
Bittner, Dror M.
Zaleski, Daniel P.
Tew, David P.
Walker, Nicholas R.
Legon, Anthony C.
Highly Unsaturated Platinum and Palladium Carbenes PtC(3) and PdC(3) Isolated and Characterized in the Gas Phase
title Highly Unsaturated Platinum and Palladium Carbenes PtC(3) and PdC(3) Isolated and Characterized in the Gas Phase
title_full Highly Unsaturated Platinum and Palladium Carbenes PtC(3) and PdC(3) Isolated and Characterized in the Gas Phase
title_fullStr Highly Unsaturated Platinum and Palladium Carbenes PtC(3) and PdC(3) Isolated and Characterized in the Gas Phase
title_full_unstemmed Highly Unsaturated Platinum and Palladium Carbenes PtC(3) and PdC(3) Isolated and Characterized in the Gas Phase
title_short Highly Unsaturated Platinum and Palladium Carbenes PtC(3) and PdC(3) Isolated and Characterized in the Gas Phase
title_sort highly unsaturated platinum and palladium carbenes ptc(3) and pdc(3) isolated and characterized in the gas phase
topic Zuschriften
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4950143/
https://www.ncbi.nlm.nih.gov/pubmed/27478275
http://dx.doi.org/10.1002/ange.201511646
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