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One-step selective hydroxylation of benzene to phenol with hydrogen peroxide catalysed by copper complexes incorporated into mesoporous silica–alumina

Benzene was hydroxylated with hydrogen peroxide (H(2)O(2)) in the presence of catalytic amounts of copper complexes in acetone to yield phenol at 298 K. At higher temperatures, phenol was further hydroxylated with H(2)O(2) by catalysis of copper complexes to yield p-benzoquinone. The kinetic study r...

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Detalles Bibliográficos
Autores principales: Yamada, Mihoko, Karlin, Kenneth D., Fukuzumi, Shunichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4951108/
https://www.ncbi.nlm.nih.gov/pubmed/27453774
http://dx.doi.org/10.1039/c5sc04312c