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A Molecular Nanotube with Three‐Dimensional π‐Conjugation

A π‐conjugated twelve‐porphyrin tube is synthesized in 32 % yield by a template‐directed coupling reaction that joins together six porphyrin dimers, forming twelve new C—C bonds. The nanotube has two bound templates, enclosing an internal volume of approximately 4.5 nm(3). Its UV/Vis/NIR absorption...

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Detalles Bibliográficos
Autores principales: Neuhaus, Patrik, Cnossen, Arjen, Gong, Juliane Q., Herz, Laura M., Anderson, Harry L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY‐VCH Verlag 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4955231/
https://www.ncbi.nlm.nih.gov/pubmed/27478266
http://dx.doi.org/10.1002/ange.201502735