An Inverted‐Sandwich Diuranium μ‐η(5):η(5)‐Cyclo‐P(5) Complex Supported by U‐P(5) δ‐Bonding

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Reaction of [U(Tren(TIPS))] [1, Tren(TIPS)=N(CH(2)CH(2)NSiiPr(3))(3)] with 0.25 equivalents of P(4) reproducibly affords the unprecedented actinide inverted sandwich cyclo‐P(5) complex [{U(Tren(TIPS))}(2)(μ‐η(5):η(5)‐cyclo‐P(5))] (2). All prior examples of cyclo‐P(5) are stabilized by d‐block metals...

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Detalles Bibliográficos
Autores principales: Gardner, Benedict M., Tuna, Floriana, McInnes, Eric J. L., McMaster, Jonathan, Lewis, William, Blake, Alexander J., Liddle, Stephen T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY‐VCH Verlag 2015
Materias:
Zuschriften
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4955234/
https://www.ncbi.nlm.nih.gov/pubmed/27478265
http://dx.doi.org/10.1002/ange.201501728

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4955234/
https://www.ncbi.nlm.nih.gov/pubmed/27478265
http://dx.doi.org/10.1002/ange.201501728

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