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An Inverted‐Sandwich Diuranium μ‐η(5):η(5)‐Cyclo‐P(5) Complex Supported by U‐P(5) δ‐Bonding
Reaction of [U(Tren(TIPS))] [1, Tren(TIPS)=N(CH(2)CH(2)NSiiPr(3))(3)] with 0.25 equivalents of P(4) reproducibly affords the unprecedented actinide inverted sandwich cyclo‐P(5) complex [{U(Tren(TIPS))}(2)(μ‐η(5):η(5)‐cyclo‐P(5))] (2). All prior examples of cyclo‐P(5) are stabilized by d‐block metals...
Autores principales: | Gardner, Benedict M., Tuna, Floriana, McInnes, Eric J. L., McMaster, Jonathan, Lewis, William, Blake, Alexander J., Liddle, Stephen T. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY‐VCH Verlag
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4955234/ https://www.ncbi.nlm.nih.gov/pubmed/27478265 http://dx.doi.org/10.1002/ange.201501728 |
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