Ca(OH)(2)-Catalyzed Condensation of Aldehydes with Methyl ketones in Dilute Aqueous Ethanol: A Comprehensive Access to α,β-Unsaturated Ketones

Cheap, abundant but seldom-employed Ca(OH)(2) was found to be an excellent low-loading (5–10 mol%) catalyst for Claisen-Schmidt condensation of aldehydes with methyl ketones under mild conditions. It was interesting that dilute aqueous ethanol (20 v/v%) was unexpectedly discovered to be the optimal...

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Detalles Bibliográficos
Autores principales: Yu, Lei, Han, Mengting, Luan, Jie, Xu, Lin, Ding, Yuanhua, Xu, Qing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4957220/
https://www.ncbi.nlm.nih.gov/pubmed/27443482
http://dx.doi.org/10.1038/srep30432

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4957220/
https://www.ncbi.nlm.nih.gov/pubmed/27443482
http://dx.doi.org/10.1038/srep30432

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