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Distinct coordination geometries in bis­[N,N-bis­(2-meth­oxy­eth­yl)di­thio­carbamato-κ(2) S,S′]di­phenyltin(IV) and bis­[N-(2-meth­oxy­eth­yl)-N-methyl­dithio­carbamato-κ(2) S,S′]di­phenyl­tin(IV): crystal structures and Hirshfeld surface analysis

The crystal and mol­ecular structures of two di­phenyl­tin bis­(di­thio­carbamate)s, [Sn(C(6)H(5))(2)(C(5)H(10)NOS(2))(2)], (I), and [Sn(C(6)H(5))(2)(C(7)H(14)NO(2)S(2))(2)], (II), are described. In (I), in which the metal atom lies on a twofold rotation axis, the di­thio­carbamate ligand coordinate...

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Detalles Bibliográficos
Autores principales: Mohamad, Rapidah, Awang, Normah, Jotani, Mukesh M., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4971856/
https://www.ncbi.nlm.nih.gov/pubmed/27536397
http://dx.doi.org/10.1107/S2056989016011385