On the mechanism of imine elimination from Fischer tungsten carbene complexes

(Aminoferrocenyl)(ferrocenyl)carbene(pentacarbonyl)tungsten(0) (CO)(5)W=C(NHFc)Fc (W(CO)(5)(E-2)) is synthesized by nucleophilic substitution of the ethoxy group of (CO)(5)W=C(OEt)Fc (M(CO)(5)(1(Et))) by ferrocenyl amide Fc-NH(–) (Fc = ferrocenyl). W(CO)(5)(E-2) thermally and photochemically elimina...

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Detalles Bibliográficos
Autores principales: Veit, Philipp, Förster, Christoph, Heinze, Katja
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4979739/
https://www.ncbi.nlm.nih.gov/pubmed/27559381
http://dx.doi.org/10.3762/bjoc.12.125

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4979739/
https://www.ncbi.nlm.nih.gov/pubmed/27559381
http://dx.doi.org/10.3762/bjoc.12.125

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