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On the mechanism of imine elimination from Fischer tungsten carbene complexes
(Aminoferrocenyl)(ferrocenyl)carbene(pentacarbonyl)tungsten(0) (CO)(5)W=C(NHFc)Fc (W(CO)(5)(E-2)) is synthesized by nucleophilic substitution of the ethoxy group of (CO)(5)W=C(OEt)Fc (M(CO)(5)(1(Et))) by ferrocenyl amide Fc-NH(–) (Fc = ferrocenyl). W(CO)(5)(E-2) thermally and photochemically elimina...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4979739/ https://www.ncbi.nlm.nih.gov/pubmed/27559381 http://dx.doi.org/10.3762/bjoc.12.125 |