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Synergistic chiral iminium and palladium catalysis: Highly regio- and enantioselective [3 + 2] annulation reaction of 2-vinylcyclopropanes with enals

A cooperative catalytic strategy of chiral iminium catalysis by regioselective activation of the C=C bond in enals and a transition metal promoting to open the 2-vinylcyclopropanes for highly regio- and enantioselective [3 + 2] cycloaddition reaction of 2-vinylcyclopropanes with α,β-unsaturated alde...

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Detalles Bibliográficos
Autores principales: Zhu, Haipan, Du, Peile, Li, Jianjun, Liao, Ziyang, Liu, Guohua, Li, Hao, Wang, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4979765/
https://www.ncbi.nlm.nih.gov/pubmed/27559383
http://dx.doi.org/10.3762/bjoc.12.127