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The EIMS fragmentation mechanisms of the sesquiterpenes corvol ethers A and B, epi-cubebol and isodauc-8-en-11-ol

Farnesyl diphosphate (FPP) and all fifteen positional isomers of ((13)C(1))FPP were enzymatically converted by the bacterial terpene cyclases corvol ether synthase from Kitasatospora setae, the epi-cubebol synthase from Streptosporangium roseum, and the isodauc-8-en-11-ol synthase from Streptomyces...

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Detalles Bibliográficos
Autores principales: Rabe, Patrick, Dickschat, Jeroen S
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4979868/
https://www.ncbi.nlm.nih.gov/pubmed/27559388
http://dx.doi.org/10.3762/bjoc.12.132