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Stereodynamic tetrahydrobiisoindole “NU-BIPHEP(O)”s: functionalization, rotational barriers and non-covalent interactions

Stereodynamic ligands offer intriguing possibilities in enantioselective catalysis. “NU-BIPHEPs” are a class of stereodynamic diphosphine ligands which are easily accessible via rhodium-catalyzed double [2 + 2 + 2] cycloadditions. This study explores the preparation of differently functionalized “NU...

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Detalles Bibliográficos
Autores principales: Storch, Golo, Pallmann, Sebastian, Rominger, Frank, Trapp, Oliver
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4979906/
https://www.ncbi.nlm.nih.gov/pubmed/27559397
http://dx.doi.org/10.3762/bjoc.12.141