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Flow carbonylation of sterically hindered ortho-substituted iodoarenes

The flow synthesis of ortho-substituted carboxylic acids, using carbon monoxide gas, has been studied for a number of substrates. The optimised conditions make use of a simple catalyst system compromising of triphenylphosphine as the ligand and palladium acetate as the pre-catalyst. Carbon monoxide...

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Detalles Bibliográficos
Autores principales: Mallia, Carl J, Walter, Gary C, Baxendale, Ian R
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4979912/
https://www.ncbi.nlm.nih.gov/pubmed/27559403
http://dx.doi.org/10.3762/bjoc.12.147