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A Step in Between: [Sn(3)Bi(3)](5−) and Its Structural Relationship to [Sn(3)Bi(5)](3−) and [Sn(4)Bi(4)](4−)
Extraction of “RbSnBi” in liquid ammonia yielded the cluster anion [Sn(3)Bi(5)](3−), which could be crystallized in the compound [Rb@[2.2.2]crypt](3)[Sn(3)Bi(5)]⋅8.87 NH(3). This anion is found to be derived from the formerly reported [Sn(4)Bi(4)](4−) by the formal substitution of one tin atom by bi...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4981049/ https://www.ncbi.nlm.nih.gov/pubmed/27547638 http://dx.doi.org/10.1002/open.201600037 |