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A Step in Between: [Sn(3)Bi(3)](5−) and Its Structural Relationship to [Sn(3)Bi(5)](3−) and [Sn(4)Bi(4)](4−)

Extraction of “RbSnBi” in liquid ammonia yielded the cluster anion [Sn(3)Bi(5)](3−), which could be crystallized in the compound [Rb@[2.2.2]crypt](3)[Sn(3)Bi(5)]⋅8.87 NH(3). This anion is found to be derived from the formerly reported [Sn(4)Bi(4)](4−) by the formal substitution of one tin atom by bi...

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Detalles Bibliográficos
Autores principales: Friedrich, Ute, Korber, Nikolaus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4981049/
https://www.ncbi.nlm.nih.gov/pubmed/27547638
http://dx.doi.org/10.1002/open.201600037