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(BB)-Carboryne Complex of Ruthenium: Synthesis by Double B–H Activation at a Single Metal Center

[Image: see text] The first example of a transition metal (BB)-carboryne complex containing two boron atoms of the icosahedral cage connected to a single exohedral metal center (POBBOP)Ru(CO)(2) (POBBOP = 1,7-OP(i-Pr)(2)-2,6-dehydro-m-carborane) was synthesized by double B–H activation within the st...

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Detalles Bibliográficos
Autores principales: Eleazer, Bennett J., Smith, Mark D., Popov, Alexey A., Peryshkov, Dmitry V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4999960/
https://www.ncbi.nlm.nih.gov/pubmed/27526855
http://dx.doi.org/10.1021/jacs.6b05172