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(BB)-Carboryne Complex of Ruthenium: Synthesis by Double B–H Activation at a Single Metal Center
[Image: see text] The first example of a transition metal (BB)-carboryne complex containing two boron atoms of the icosahedral cage connected to a single exohedral metal center (POBBOP)Ru(CO)(2) (POBBOP = 1,7-OP(i-Pr)(2)-2,6-dehydro-m-carborane) was synthesized by double B–H activation within the st...
Autores principales: | Eleazer, Bennett J., Smith, Mark D., Popov, Alexey A., Peryshkov, Dmitry V. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2016
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4999960/ https://www.ncbi.nlm.nih.gov/pubmed/27526855 http://dx.doi.org/10.1021/jacs.6b05172 |
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