How the Proximal Pocket May Influence the Enantiospecificities of Chloroperoxidase-Catalyzed Epoxidations of Olefins

Chloroperoxidase-catalyzed enantiospecific epoxidations of olefins are of significant biotechnological interest. Typical enantiomeric excesses are in the range of 66%–97% and translate into free energy differences on the order of 1 kcal/mol. These differences are generally attributed to the effect o...

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Detalles Bibliográficos
Autores principales: Morozov, Alexander N., Chatfield, David C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5000694/
https://www.ncbi.nlm.nih.gov/pubmed/27517911
http://dx.doi.org/10.3390/ijms17081297

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5000694/
https://www.ncbi.nlm.nih.gov/pubmed/27517911
http://dx.doi.org/10.3390/ijms17081297

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