Enhancement of Tb(III)–Cu(II) Single‐Molecule Magnet Performance through Structural Modification

We report a series of 3d–4f complexes {Ln(2)Cu(3)(H(3)L)(2)X(n)} (X=OAc(−), Ln=Gd, Tb or X=NO(3) (−), Ln=Gd, Tb, Dy, Ho, Er) using the 2,2′‐(propane‐1,3‐diyldiimino)bis[2‐(hydroxylmethyl)propane‐1,3‐diol] (H(6)L) pro‐ligand. All complexes, except that in which Ln=Gd, show slow magnetic relaxation in...

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Detalles Bibliográficos
Autores principales: Heras Ojea, María José, Milway, Victoria A., Velmurugan, Gunasekaran, Thomas, Lynne H., Coles, Simon J., Wilson, Claire, Wernsdorfer, Wolfgang, Rajaraman, Gopalan, Murrie, Mark
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5008113/
https://www.ncbi.nlm.nih.gov/pubmed/27484259
http://dx.doi.org/10.1002/chem.201601971

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5008113/
https://www.ncbi.nlm.nih.gov/pubmed/27484259
http://dx.doi.org/10.1002/chem.201601971

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