Cargando…

Enhancement of Tb(III)–Cu(II) Single‐Molecule Magnet Performance through Structural Modification

We report a series of 3d–4f complexes {Ln(2)Cu(3)(H(3)L)(2)X(n)} (X=OAc(−), Ln=Gd, Tb or X=NO(3) (−), Ln=Gd, Tb, Dy, Ho, Er) using the 2,2′‐(propane‐1,3‐diyldiimino)bis[2‐(hydroxylmethyl)propane‐1,3‐diol] (H(6)L) pro‐ligand. All complexes, except that in which Ln=Gd, show slow magnetic relaxation in...

Descripción completa

Detalles Bibliográficos
Autores principales:	Heras Ojea, María José, Milway, Victoria A., Velmurugan, Gunasekaran, Thomas, Lynne H., Coles, Simon J., Wilson, Claire, Wernsdorfer, Wolfgang, Rajaraman, Gopalan, Murrie, Mark
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2016
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5008113/ https://www.ncbi.nlm.nih.gov/pubmed/27484259 http://dx.doi.org/10.1002/chem.201601971

Ejemplares similares

Importance of an Axial Ln(III)–F Bond across the Lanthanide Series and Single-Molecule Magnet Behavior in the Ce and Nd Analogues
por: Regincós Martí, Emma, et al.
Publicado: (2022)

Directed Synthesis of {Mn18Cu6} Heterometallic Complexes**
por: Milway, Victoria A, et al.
Publicado: (2013)

Ferrotoroidic ground state in a heterometallic {Cr(III)Dy(III)(6)} complex displaying slow magnetic relaxation
por: Vignesh, Kuduva R., et al.
Publicado: (2017)

Insight into D (6h) Symmetry: Targeting Strong Axiality in Stable Dysprosium(III) Hexagonal Bipyramidal Single‐Ion Magnets
por: Canaj, Angelos B., et al.
Publicado: (2019)

Validation of Ab‐Initio‐Predicted Magnetic Anisotropies and Magneto‐structural Correlations in Linear Hetero‐trinuclear Dy(III)‐Ni(II) (2) Compounds
por: Comba, Peter, et al.
Publicado: (2021)

Single-molecule magnet behavior in 2,2’-bipyrimidine-bridged dilanthanide complexes
por: Yu, Wen, et al.
Publicado: (2016)

The Effect of Crystal Packing and Re(IV) Ions on the Magnetisation Relaxation of [Mn(6)]-Based Molecular Magnets
por: Martínez-Lillo, José, et al.
Publicado: (2015)

Highly Oxidized States of Phthalocyaninato Terbium(III) Multiple‐Decker Complexes Showing Structural Deformations, Biradical Properties and Decreases in Magnetic Anisotropy
por: Horii, Yoji, et al.
Publicado: (2020)

Antiferromagnetic coupling of TbPc(2) molecules to ultrathin Ni and Co films
por: Klar, David, et al.
Publicado: (2013)

Modulating magnetic anisotropy in Ln(iii) single-ion magnets using an external electric field
por: Sarkar, Arup, et al.
Publicado: (2020)

Strategies to Design Single-Molecule Toroics Using Triangular {Ln(3)}(n) Motifs
por: Vignesh, Kuduva R., et al.
Publicado: (2021)

Deciphering the origin of giant magnetic anisotropy and fast quantum tunnelling in Rhenium(IV) single-molecule magnets
por: Singh, Saurabh Kumar, et al.
Publicado: (2016)

Analysis of the Magnetic Coupling in a Mn(II)‐U(V)‐Mn(II) Single Molecule Magnet
por: Dey, Sourav, et al.
Publicado: (2022)

Cu and Hydroquinone for the Trifluoromethylation of Unprotected Phenols
por: Pletz, Jakob, et al.
Publicado: (2018)

Quantum tunnelling of the magnetisation in single-molecule magnet isotopologue dimers
por: Moreno-Pineda, Eufemio, et al.
Publicado: (2019)

Exploiting host–guest chemistry to manipulate magnetic interactions in metallosupramolecular M(4)L(6) tetrahedral cages
por: Scott, Aaron J., et al.
Publicado: (2021)

Non‐Heme‐Iron‐Mediated Selective Halogenation of Unactivated Carbon−Hydrogen Bonds
por: Bleher, Katharina, et al.
Publicado: (2021)

An air-stable Dy(iii) single-ion magnet with high anisotropy barrier and blocking temperature
por: Gupta, Sandeep K., et al.
Publicado: (2016)

In-depth investigation of large axial magnetic anisotropy in monometallic 3d complexes using frequency domain magnetic resonance and ab initio methods: a study of trigonal bipyramidal Co(ii)
por: Hay, Moya A., et al.
Publicado: (2019)

Hydrogen bonding patterns in the cocrystals of 5-nitrouracil with several donor and acceptor molecules
por: Thomas, Reji, et al.
Publicado: (2005)

Crystal structure of a Tb(III)–Cu(II) glycinehydroxamate 15-metallacrown-5 sulfate complex
por: Pavlishchuk, Anna V., et al.
Publicado: (2021)

Nanoscale patterning of a self-assembled monolayer by modification of the molecule–substrate bond
por: Shen, Cai, et al.
Publicado: (2014)

Modification of a single-molecule AFM probe with highly defined surface functionality
por: Long, Fei, et al.
Publicado: (2014)

Effects of Salmonella enteritidis Vaccination on the Expression of Innate Immune Molecules and Histone Modifications in the Follicular Theca of Laying Hens
por: Kang, Ye, et al.
Publicado: (2019)

Electroburning of few-layer graphene flakes, epitaxial graphene, and turbostratic graphene discs in air and under vacuum
por: Candini, Andrea, et al.
Publicado: (2015)

Modification of a SERS-active Ag surface to promote adsorption of charged analytes: effect of Cu(2+) ions
por: Ranishenka, Bahdan V, et al.
Publicado: (2021)

Synthesis of CuO and Cu(3)N Nanoparticles in and on Hollow Silica Spheres
por: Deshmukh, Rupali, et al.
Publicado: (2013)

Deciphering the origin of million-fold reactivity observed for the open core diiron [HO–Fe(III)–O–Fe(IV)[double bond, length as m-dash]O](2+) species towards C–H bond activation: role of spin-states, spin-coupling, and spin-cooperation
por: Ansari, Mursaleem, et al.
Publicado: (2020)

Exchange-bias quantum tunnelling in a CO(2)-based Dy(4)-single molecule magnet
por: Pineda, Eufemio Moreno, et al.
Publicado: (2017)

Supported Cu(II) Single‐Ion Catalyst for Total Carbon Utilization of C(2) and C(3) Biomass‐Based Platform Molecules in the N‐Formylation of Amines
por: Dai, Xingchao, et al.
Publicado: (2021)

In silico design to enhance the barrier height for magnetization reversal in Dy(iii) sandwich complexes by stitching them under the umbrella of corannulene
por: Sharma, Tanu, et al.
Publicado: (2021)

Magnetic Nature of the Cr(III)–Ln(III) Interactions in [Cr(III) (2)Ln(III) (3)] Clusters with Slow Magnetic Relaxation
por: Zhao, Xiao‐Qing, et al.
Publicado: (2018)

CuO and Ag(2)O/CuO Catalyzed Oxidation of Aldehydes to the Corresponding Carboxylic Acids by Molecular Oxygen
por: Tian, Qingyong, et al.
Publicado: (2008)

Molecular Quantum Spintronics: Supramolecular Spin Valves Based on Single-Molecule Magnets and Carbon Nanotubes
por: Urdampilleta, Matias, et al.
Publicado: (2011)

The Coordination Behaviour of Cu(I) Photosensitizers Bearing Multidentate Ligands Investigated by X‐ray Absorption Spectroscopy
por: Rentschler, Martin, et al.
Publicado: (2020)

Influence of the supramolecular architecture on the magnetic properties of a Dy(III) single-molecule magnet: an ab initio investigation
por: Jung, Julie, et al.
Publicado: (2014)

Effect of the CuAl(2)O(4) and CuAlO(2) Phases in Catalytic Wet Air Oxidation of ETBE and TAME using CuO/γ‐Al(2)O(3) catalysts
por: Sánchez‐Trinidad, Cecilia, et al.
Publicado: (2019)

Stability of Ag(III) towards Halides in Organosilver(III) Complexes
por: Joven‐Sancho, Daniel, et al.
Publicado: (2021)

Incorporation of Tb and Gd improves the diagnostic functionality of magnetotactic bacteria
por: Gandarias, Lucía, et al.
Publicado: (2023)

Accessing Bioactive Hydrazones by the Hydrohydrazination of Terminal Alkynes Catalyzed by Gold(I) Acyclic Aminooxy Carbene Complexes and Their Gold(I) Arylthiolato and Gold(III) Tribromo Derivatives: A Combined Experimental and Computational Study
por: Singh, Jyoti, et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_b1ss1u10qu6qaie4pl68ud2bk0