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Highly Efficient and Selective Hydrogenation of Aldehydes: A Well-Defined Fe(II) Catalyst Exhibits Noble-Metal Activity

[Image: see text] The synthesis and application of [Fe(PNP(Me)-iPr)(CO)(H)(Br)] and [Fe(PNP(Me)-iPr)(H)(2)(CO)] as catalysts for the homogeneous hydrogenation of aldehydes is described. These systems were found to be among the most efficient catalysts for this process reported to date and constitute...

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Detalles Bibliográficos
Autores principales: Gorgas, Nikolaus, Stöger, Berthold, Veiros, Luis F., Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5023089/
https://www.ncbi.nlm.nih.gov/pubmed/27660732
http://dx.doi.org/10.1021/acscatal.6b00436