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Rate Constants and Activation Energies for Gas‐Phase Reactions of Three Cyclic Volatile Methyl Siloxanes with the Hydroxyl Radical

Reaction with hydroxyl radicals (OH) is the major pathway for removal of cyclic volatile methyl siloxanes (cVMS) from air. We present new measurements of second‐order rate constants for reactions of the cVMS octamethylcyclotetrasiloxane (D(4)), decamethylcyclopentasiloxane (D(5)), and dodecamethylcy...

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Detalles Bibliográficos
Autores principales: Safron, Andreas, Strandell, Michael, Kierkegaard, Amelie, Macleod, Matthew
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5029797/
https://www.ncbi.nlm.nih.gov/pubmed/27708500
http://dx.doi.org/10.1002/kin.20919