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Structure and cation distribution in perovskites with small cations at the A site: the case of ScCoO(3)
We synthesize ScCoO(3) perovskite and its solid solutions, ScCo(1−x)Fe(x)O(3) and ScCo(1−x)Cr(x)O(3), under high pressure (6 GPa) and high temperature (1570 K) conditions. We find noticeable shifts from the stoichiometric compositions, expressed as (Sc(1−x)M(x))MO(3) with x = 0.05–0.11 and M = Co, (...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Taylor & Francis
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5036463/ https://www.ncbi.nlm.nih.gov/pubmed/27877762 http://dx.doi.org/10.1088/1468-6996/16/2/024801 |