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Structure and cation distribution in perovskites with small cations at the A site: the case of ScCoO(3)

We synthesize ScCoO(3) perovskite and its solid solutions, ScCo(1−x)Fe(x)O(3) and ScCo(1−x)Cr(x)O(3), under high pressure (6 GPa) and high temperature (1570 K) conditions. We find noticeable shifts from the stoichiometric compositions, expressed as (Sc(1−x)M(x))MO(3) with x = 0.05–0.11 and M = Co, (...

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Detalles Bibliográficos
Autores principales: Yi, Wei, Presniakov, Igor A, Sobolev, Alexey V, Glazkova, Yana S, Matsushita, Yoshitaka, Tanaka, Masahiko, Kosuda, Kosuke, Tsujimoto, Yoshihiro, Yamaura, Kazunari, Belik, Alexei A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Taylor & Francis 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5036463/
https://www.ncbi.nlm.nih.gov/pubmed/27877762
http://dx.doi.org/10.1088/1468-6996/16/2/024801