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Diffusion-Controlled Rotation of Triptycene in a Metal–Organic Framework (MOF) Sheds Light on the Viscosity of MOF-Confined Solvent

[Image: see text] Artificial molecular machines are expected to operate under conditions of very low Reynolds numbers with inertial forces orders of magnitude smaller than viscous forces. While these conditions are relatively well understood in bulk fluids, opportunities to assess the role of viscou...

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Detalles Bibliográficos
Autores principales: Jiang, Xing, Duan, Hai-Bao, Khan, Saeed I., Garcia-Garibay, Miguel A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5043434/
https://www.ncbi.nlm.nih.gov/pubmed/27725958
http://dx.doi.org/10.1021/acscentsci.6b00168