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Synthesis of Cis,syndiotactic A-alt-B Copolymers from Two Enantiomerically Pure Trans-2,3-Disubstituted-5,6-Norbornenes

[Image: see text] Cis,syndiotacticA-alt-B copolymers, where A and B are two enantiomerically pure trans-2,3-disubstituted-5,6-norbornenes with “opposite” chiralities, can be prepared with stereogenic-at-metal initiators of the type M(NR)(CHR′)(OR”)(pyrrolide). Formation of a high percentage of alter...

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Detalles Bibliográficos
Autores principales: Jang, Eun Sil, John, Jeremy M., Schrock, Richard R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5043441/
https://www.ncbi.nlm.nih.gov/pubmed/27725961
http://dx.doi.org/10.1021/acscentsci.6b00200