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Structural diversity of halocarbonyl molybdenum and tungsten PNP pincer complexes through ligand modifications

This work presents a comparative study of a series of halocarbonyl Mo(ii) and W(ii) complexes of the types [M(PNP)(CO)(3)X]X and [M(PNP)(CO)(2)X(2)] (M = Mo, W; X = I, Br), featuring PNP pincer ligands based on a 2,6-diaminopyridine scaffold. The complexes were prepared and fully characterized. The...

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Detalles Bibliográficos
Autores principales: de Aguiar, Sara R. M. M., Stöger, Berthold, Pittenauer, Ernst, Allmaier, Günter, Veiros, Luis F., Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5048400/
https://www.ncbi.nlm.nih.gov/pubmed/27513832
http://dx.doi.org/10.1039/c6dt02251k