Crystal structures of the two epimers from the unusual thermal C6-epimerization of 5-oxo-1,2,3,5,5a,6,7,9b-octa­hydro-7,9a-ep­oxy­pyrrolo­[2,1-a]iso­indole-6-carb­oxy­lic acid, 5a(RS),6(SR),7(RS),9a(SR),9b(SR) and 5a(RS),6(RS),7(RS),9a(SR),9b(SR)

The isomeric title compounds, C(12)H(13)NO(4) (Ia) and C(12)H(13)NO(4) (IIa), the products of an usual thermal C6-epimerization of 5-oxo-1,2,3,5,5a,6,7,9b-octa­hydro-7,9a-ep­oxy­pyrrolo­[2,1-a]iso­indole-6-carb­oxy­lic acid, represent the two different diastereomers and have very similar mol­ecular...

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Detalles Bibliográficos
Autores principales: Poplevin, Dmitry S., Zubkov, Fedor I., Dorovatovskii, Pavel V., Zubavichus, Yan V., Khrustalev, Victor N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050770/
https://www.ncbi.nlm.nih.gov/pubmed/27746935
http://dx.doi.org/10.1107/S2056989016014420

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050770/
https://www.ncbi.nlm.nih.gov/pubmed/27746935
http://dx.doi.org/10.1107/S2056989016014420

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