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Crystal structures of the two epimers from the unusual thermal C6-epimerization of 5-oxo-1,2,3,5,5a,6,7,9b-octahydro-7,9a-epoxypyrrolo[2,1-a]isoindole-6-carboxylic acid, 5a(RS),6(SR),7(RS),9a(SR),9b(SR) and 5a(RS),6(RS),7(RS),9a(SR),9b(SR)

The isomeric title compounds, C(12)H(13)NO(4) (Ia) and C(12)H(13)NO(4) (IIa), the products of an usual thermal C6-epimerization of 5-oxo-1,2,3,5,5a,6,7,9b-octahydro-7,9a-epoxypyrrolo[2,1-a]isoindole-6-carboxylic acid, represent the two different diastereomers and have very similar molecular...

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Detalles Bibliográficos
Autores principales:	Poplevin, Dmitry S., Zubkov, Fedor I., Dorovatovskii, Pavel V., Zubavichus, Yan V., Khrustalev, Victor N.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2016
Materias:	Research Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050770/ https://www.ncbi.nlm.nih.gov/pubmed/27746935 http://dx.doi.org/10.1107/S2056989016014420

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