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Polynuclear Gold [Au(I)](4), [Au(I)](8), and Bimetallic [Au(I) (4)Ag(I)] Complexes: C−H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines
The synthesis of tetranuclear gold complexes, a structurally unprecedented octanuclear complex with a planar [Au(I) (8)] core, and pentanuclear [Au(I) (4)M(I)] (M=Cu, Ag) complexes is presented. The linear [Au(I) (4)] complex undergoes C−H functionalization of carbonyl compounds under mild reaction...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5053296/ https://www.ncbi.nlm.nih.gov/pubmed/27167611 http://dx.doi.org/10.1002/anie.201603200 |