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Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates

The Rauhut–Currier (RC) reaction represents an efficient method for the construction of carbon–carbon bond in organic synthesis. However, the RC reactions involving allenoate substrates are very rare, and in particular, asymmetric intramolecular RC reaction of allenoates is yet to be discovered. Her...

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Detalles Bibliográficos
Autores principales: Yao, Weijun, Dou, Xiaowei, Wen, Shan, Wu, Ji'en, Vittal, Jagadese J., Lu, Yixin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5059449/
https://www.ncbi.nlm.nih.gov/pubmed/27698487
http://dx.doi.org/10.1038/ncomms13024