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Unconventional exo selectivity in thermal normal-electron-demand Diels–Alder reactions

The Diels–Alder reaction is a useful tool for generating functionalized chiral molecules through the concerted cycloaddition of dienes and dienophiles leading to six-membered rings. Traditionally, the selective predictions of the products rely heavily on consideration of the secondary orbital intera...

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Detalles Bibliográficos
Autores principales: Ho, Guo-Ming, Huang, Ci-Jhang, Li, Elise Yu-Tzu, Hsu, Sheng-Kai, Wu, Ti, Zulueta, Medel Manuel L., Wu, Kevin Binchia, Hung, Shang-Cheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5059706/
https://www.ncbi.nlm.nih.gov/pubmed/27731360
http://dx.doi.org/10.1038/srep35147