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Multistate Redox Switching and Near-Infrared Electrochromism Based on a Star-Shaped Triruthenium Complex with a Triarylamine Core

A star-shaped cyclometalated triruthenium complex 2(PF(6))(n) (n = 3 and 4) with a triarylamine core was synthesized, which functions as a molecular switch with five well-separated redox states in both solution and film states. The single-crystal X-ray structure of 2(PF(6))(3) is presented. This com...

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Detalles Bibliográficos
Autores principales: Tang, Jian-Hong, He, Yan-Qin, Shao, Jiang-Yang, Gong, Zhong-Liang, Zhong, Yu-Wu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5059756/
https://www.ncbi.nlm.nih.gov/pubmed/27731404
http://dx.doi.org/10.1038/srep35253