Cargando…

Simple phosphinate ligands access zinc clusters identified in the synthesis of zinc oxide nanoparticles

The bottom-up synthesis of ligand-stabilized functional nanoparticles from molecular precursors is widely applied but is difficult to study mechanistically. Here we use (31)P NMR spectroscopy to follow the trajectory of phosphinate ligands during the synthesis of a range of ligated zinc oxo clusters...

Descripción completa

Detalles Bibliográficos
Autores principales: Pike, Sebastian D., White, Edward R., Shaffer, Milo S. P., Williams, Charlotte K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5065624/
https://www.ncbi.nlm.nih.gov/pubmed/27734828
http://dx.doi.org/10.1038/ncomms13008