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Simple phosphinate ligands access zinc clusters identified in the synthesis of zinc oxide nanoparticles
The bottom-up synthesis of ligand-stabilized functional nanoparticles from molecular precursors is widely applied but is difficult to study mechanistically. Here we use (31)P NMR spectroscopy to follow the trajectory of phosphinate ligands during the synthesis of a range of ligated zinc oxo clusters...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5065624/ https://www.ncbi.nlm.nih.gov/pubmed/27734828 http://dx.doi.org/10.1038/ncomms13008 |