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Site‐Selective Acylations with Tailor‐Made Catalysts

The acylation of alcohols catalyzed by N,N‐dimethylamino pyridine (DMAP) is, despite its widespread use, sometimes confronted with substrate‐specific problems: For example, target compounds with multiple hydroxy groups may show insufficient selectivity for one hydroxyl, and the resulting product mix...

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Detalles Bibliográficos
Autores principales: Huber, Florian, Kirsch, Stefan F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5069569/
https://www.ncbi.nlm.nih.gov/pubmed/26970553
http://dx.doi.org/10.1002/chem.201600790