Strong Exchange Coupling in a Trimetallic Radical‐Bridged Cobalt(II)‐Hexaazatrinaphthylene Complex

Reducing hexaazatrinaphthylene (HAN) with potassium in the presence of 18‐c‐6 produces [{K(18‐c‐6)}HAN], which contains the S=1/2 radical [HAN](.−). The [HAN](.−) radical can be transferred to the cobalt(II) amide [Co{N(SiMe(3))(2)}(2)], forming [K(18‐c‐6)][(HAN){Co(N′′)(2)}(3)]; magnetic measuremen...

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Detalles Bibliográficos
Autores principales: Moilanen, Jani O., Chilton, Nicholas F., Day, Benjamin M., Pugh, Thomas, Layfield, Richard A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5071680/
https://www.ncbi.nlm.nih.gov/pubmed/26997130
http://dx.doi.org/10.1002/anie.201600694

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5071680/
https://www.ncbi.nlm.nih.gov/pubmed/26997130
http://dx.doi.org/10.1002/anie.201600694

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