Singly versus Doubly Reduced Nickel Porphyrins for Proton Reduction: Experimental and Theoretical Evidence for a Homolytic Hydrogen‐Evolution Reaction

A nickel(II) porphyrin Ni‐P (P=porphyrin) bearing four meso‐C(6)F(5) groups to improve solubility and activity was used to explore different hydrogen‐evolution‐reaction (HER) mechanisms. Doubly reduced Ni‐P ([Ni‐P](2−)) was involved in H(2) production from acetic acid, whereas a singly reduced speci...

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Detalles Bibliográficos
Autores principales: Han, Yongzhen, Fang, Huayi, Jing, Huize, Sun, Huiling, Lei, Haitao, Lai, Wenzhen, Cao, Rui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5071703/
https://www.ncbi.nlm.nih.gov/pubmed/27028563
http://dx.doi.org/10.1002/anie.201510001

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5071703/
https://www.ncbi.nlm.nih.gov/pubmed/27028563
http://dx.doi.org/10.1002/anie.201510001

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