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Singly versus Doubly Reduced Nickel Porphyrins for Proton Reduction: Experimental and Theoretical Evidence for a Homolytic Hydrogen‐Evolution Reaction

A nickel(II) porphyrin Ni‐P (P=porphyrin) bearing four meso‐C(6)F(5) groups to improve solubility and activity was used to explore different hydrogen‐evolution‐reaction (HER) mechanisms. Doubly reduced Ni‐P ([Ni‐P](2−)) was involved in H(2) production from acetic acid, whereas a singly reduced speci...

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Detalles Bibliográficos
Autores principales:	Han, Yongzhen, Fang, Huayi, Jing, Huize, Sun, Huiling, Lei, Haitao, Lai, Wenzhen, Cao, Rui
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2016
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5071703/ https://www.ncbi.nlm.nih.gov/pubmed/27028563 http://dx.doi.org/10.1002/anie.201510001

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