New Initiation Modes for Directed Carbonylative C–C Bond Activation: Rhodium-Catalyzed (3 + 1 + 2) Cycloadditions of Aminomethylcyclopropanes

[Image: see text] Under carbonylative conditions, neutral Rh(I)-systems modified with weak donor ligands (AsPh(3) or 1,4-oxathiane) undergo N-Cbz, N-benzoyl, or N-Ts directed insertion into the proximal C–C bond of aminomethylcyclopropanes to generate rhodacyclopentanone intermediates. These are tra...

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Detalles Bibliográficos
Autores principales: Wang, Gang-Wei, McCreanor, Niall G., Shaw, Megan H., Whittingham, William G., Bower, John F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5073370/
https://www.ncbi.nlm.nih.gov/pubmed/27709913
http://dx.doi.org/10.1021/jacs.6b08608

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5073370/
https://www.ncbi.nlm.nih.gov/pubmed/27709913
http://dx.doi.org/10.1021/jacs.6b08608

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