Isomerization of Cyclooctadiene to Cyclooctyne with a Zinc/Zirconium Heterobimetallic Complex

Reaction of a zinc/zirconium heterobimetallic complex with 1,5‐cyclooctadiene (1,5‐COD) results in slow isomerization to 1,3‐cyclooctadiene (1,3‐COD), along with the formation of a new complex that includes a cyclooctyne ligand bridging two metal centers. While analogous magnesium/zirconium and alum...

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Detalles Bibliográficos
Autores principales: Butler, Michael J., White, Andrew J. P., Crimmin, Mark R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5074263/
https://www.ncbi.nlm.nih.gov/pubmed/27071992
http://dx.doi.org/10.1002/anie.201601758

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5074263/
https://www.ncbi.nlm.nih.gov/pubmed/27071992
http://dx.doi.org/10.1002/anie.201601758

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